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Fluoride Anion Recognition by a Multifunctional Urea Derivative: An Experimental and Theoretical Study

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Schiller, Jana ; Perez-Ruiz, Raul ; Sampedro, D. ; Marqués-López, Eugenia ; Herrera, Raquel P. ; Diaz Diaz, David
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 19 Feb 2020 13:44


In this work we demonstrate the ability of a multifaceted N,N '-disubstituted urea to selectively recognize fluoride anion (F-) among other halides. This additional function is now added to its already reported organocatalytic and organogelator properties. The signaling mechanism relies on the formation of a charge-transfer (CT) complex between the urea-based sensor and F- in the ground state ...


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