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Interplay between J- and H-type coupling in aggregates of π-conjugated polymers: a single-molecule perspective

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Eder, Theresa ; Vogelsang, Jan ; Bange, Sebastian ; Lupton, John M.
License: Creative Commons: Attribution 3.0
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Date of publication of this fulltext: 26 Feb 2020 14:10

This publication is part of the DEAL contract with Wiley.


Strong dipole–dipole coupling within and between π‐conjugated segments shifts electronic transitions, and modifies vibronic coupling and excited‐state lifetimes. Since J‐type coupling between monomers along the conjugated‐polymer (CP) chain and H‐type coupling of chromophores between chains of a CP compete, a superposition of the spectral modifications arising from each type of coupling emerges, ...


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