[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

URN to cite this document:: urn:nbn:de:bvb:355-epub-417030
DOI to cite this document:: 10.5283/epub.41703

Hoidn, Christian M. ; Maier, Thomas M. ; Trabitsch, Karolina ; Wolf, Robert

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Date of publication of this fulltext: 26 Feb 2020 14:47

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Abstract

The activation of white phosphorus (P4) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P5 ligand by treatment with cyanide. Cobalt diorganopentaphosphido complexes have been synthesized by a ...