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Monomeric β‐Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH2 Groups (E=P, As)

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Li, Bin ; Bauer, Susanne ; Seidl, Michael ; Timoshkin, Alexey ; Scheer, Manfred
Date of publication of this fulltext: 02 Mar 2020 08:30

This publication is part of the DEAL contract with Wiley.


The pnictogenyl Group 13 compounds (Dipp(2)Nacnac)M[E(SiMe3)(2)]Cl and (Dipp(2)Nacnac)M(EH2)(2) (Dipp(2)Nacnac=HC[C(Me)N(Ar)](2), Ar: Dipp=2,6-iPr(2)C(6)H(3); M=Al, Ga, In; E=P, As) were successfully synthesized. The salt metathesis between (Dipp(2)Nacnac)MCl2 and LiE(SiMe3)(2) only led to monosubstituted compounds (Dipp(2)Nacnac)M[E(SiMe3)(2)]Cl [E=P, M=Ga(1), In (2); E=As, M=Ga (3), In (4)], ...


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