Monomeric β‐Diketiminato Group 13 Metal Dipnictogenide Complexes with Two Terminal EH2 Groups (E=P, As)

URN to cite this document:: urn:nbn:de:bvb:355-epub-417223
DOI to cite this document:: 10.5283/epub.41722

Li, Bin ; Bauer, Susanne ; Seidl, Michael ; Timoshkin, Alexey

; Scheer, Manfred

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Date of publication of this fulltext: 02 Mar 2020 08:30

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Abstract

The pnictogenyl Group 13 compounds (Dipp(2)Nacnac)M[E(SiMe3)(2)]Cl and (Dipp(2)Nacnac)M(EH2)(2) (Dipp(2)Nacnac=HC[C(Me)N(Ar)](2), Ar: Dipp=2,6-iPr(2)C(6)H(3); M=Al, Ga, In; E=P, As) were successfully synthesized. The salt metathesis between (Dipp(2)Nacnac)MCl2 and LiE(SiMe3)(2) only led to monosubstituted compounds (Dipp(2)Nacnac)M[E(SiMe3)(2)]Cl [E=P, M=Ga(1), In (2); E=As, M=Ga (3), In (4)], ...