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Synthesis and characterization of manganese triple-decker complexes

Heinl, Sebastian ; Balázs, Gábor ; Bodensteiner, Michael ; Scheer, Manfred



Abstract

The use of the highly sterically demanding Cp-BIG ligand (Cp-BIG = C-5(4-nBuC(6)H(4))(5)) and white phosphorus (P-4) enables the synthesis of new P-rich derivatives of the rare P-n ligand complexes of manganese. The obtained complexes, [{(CpMn)-Mn-BIG}(2)(mu,eta(5:5)-P-5)] (2) and [{(CpMn)-Mn-BIG}(2)(mu,eta(2:2)-P-2)(2)] (3), exhibit the highest number of P atoms in this class of manganese ...

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