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Structural and photophysical characterization of gold(I) complexes bearing naphthyl chromophores

Hobbollahi, Elnaz ; List, Manuela ; Redhammer, Günther ; Zabel, Manfred ; Monkowius, Uwe



Abstract

We prepared two chlorido-gold(I) complexes of the type L-Au-Cl bearing a naphthyl moiety: Complex 1 with L = tris-1-naphthyl-phosphine shows standard linear coordination without further aggregation in the solid state. Complex 2 with L = 2-naphthyl-isonitrile is engaged in a complex network of aurophilic and pi-pi interactions. The two complexes show similar luminescence behaviour in solution at ...

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