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A cyclo -P6 Ligand Complex for the Formation of Planar 2D Layers

Heindl, Claudia ; Peresypkina, Eugenia V. ; Lüdeker, David ; Brunklaus, Gunther ; Virovets, Alexander V. ; Scheer, Manfred


The all-phosphorus analogue of benzene, stabilized as middle deck in triple-decker complexes, is a promising building block for the formation of graphene-like sheet structures. The reaction of [(CpMo)(2)(,(6):(6)-P-6)] (1) with CuX (X=Br, I) leads to self-assembly into unprecedented 2D networks of [{(CpMo)(2)P-6}(CuBr)(4)](n) (2) and [{(CpMo)(2)P-6}(CuI)(2)](n) (3). X-ray structural analyses show ...


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