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Progress in Polyarsolyl Chemistry

Heindl, Claudia ; Peresypkina, Eugenia V. ; Virovets, Alexander V. ; Balázs, Gábor ; Scheer, Manfred


The synthesis of heteroatom analogues of the cyclopentadienyl anion Cp- is a fascinating and challenging field of research. The replacement of methine moieties by phosphorus is well investigated for the synthesis of mono-, tri- and pentaphospholyl ligands. On the other hand, arsenic derivatives are rare and 1,2,4-triarsolyl and tetraarsolyl salts are unknown. Herein, we report on the synthesis of ...


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