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The First Coordination Polymers Based on 1,3-Diphosphaferrocenes and 1,1′,2,3′,4-Pentaphosphaferrocenes

Heindl, Claudia ; Reisinger, Sabine ; Schwarzmaier, Christoph ; Rummel, Lena ; Virovets, Alexander V. ; Peresypkina, Eugenia V. ; Scheer, Manfred



Abstract

Phosphaferrocenes in combination with coinage metal salts proved to be excellent building blocks in supramolecular chemistry for the buildup of oligomeric and polymeric assemblies. The synthesis of a series of novel phosphaferrocenes containing the 1,3-P(2)C(3)iPr(3) and/or the 1,2,4-P(3)C(2)iPr(2) ligand is described herein. The self-assembly processes of the 1,3-diphospha-, 1,2,4-triphospha-, ...

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