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CT interactions of the cuboidal cluster Fe 4 S 4 . Photoredox decomposition of (C 5 H 5 ) 4 Fe 4 S 4

Vogler, Arnd



Abstract

The cluster complex (C5H5)(4)Fe4S4 formally contains Fe(III) and sulfide as constituents. In agreement with this assignment, the long-wavelength absorptions of the cluster are attributed to S2- to Fe(III) LMCT transitions. In solutions of acetonitrile, LMCT excitation of the cluster complex leads to a photoredox decomposition yielding Fe(II) and elemental sulfur. Upon a one-electron oxidation of ...

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