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Molecular Polyarsenides of the Rare-Earth Elements

Arleth, Nicholas ; Gamer, Michael T. ; Köppe, Ralf ; Konchenko, Sergey N. ; Fleischmann, Martin ; Scheer, Manfred ; Roesky, Peter W.


Reduction of [Cp*Fe(eta(5)-As-5)] with [Cp-2 '' Sm(thf)]/(Cp '' = eta(5)-1,3-(tBu)(2)C5H3) under various conditions led to [(Cp-2 '' Sm)(mu,eta(4):eta(4)-As-4)(Cp*Fe)] and [(Cp-2 '' Sm)(2)As-7-(Cp*Fe)]. Both compounds are the first polyarsenides of the rare-earth metals. [(Cp-2 '' Sm)(mu,eta(4) :eta(4)-As-4)(Cp*Fe)] is also the first d/f-triple decker sandwich complex with a purely inorganic ...


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