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Supramolecular adducts based on weak interactions between the trimeric Lewis acid complex (perfluoro-ortho-phenylene)mercury and polypnictogen complexes

Fleischmann, Martin ; Jones, James S. ; Balázs, Gábor ; Gabbaï, François P. ; Scheer, Manfred



Abstract

Reactions of the trinuclear Lewis acid perfluoro-ortho-phenylene) mercury [(o-HgC6F4)3] (1) with the polypnictogen complex [CpMo(CO)(2)(eta(3)-P-3)] (2) containing a cyclo-P-3 ligand and the series of E-2 complexes [{CpMo(CO)(2)}(2)(mu, eta(2):eta(2)-E-2)] (E = P(3a), As(3b), Sb(3c), Bi(3d)) are reported. In all cases, the reaction products show very weak interactions between the En ligand ...

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