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Metal–organic frameworks (MOFs) bring new life to hydrogen-bonding organocatalysts in confined spaces

Alegre-Requena, Juan V. ; Marqués-López, Eugenia ; Herrera, Raquel P. ; Díaz, David Díaz



Abstract

Hydrogen-bonding organocatalysis has emerged as a promising biomimetic alternative to Lewis acid catalysis. Urea, thiourea and squaramide moieties represent the most common hydrogen-bond donors used for the preparation of these catalysts. However, their significant tendency to undergo self-quenching (self-aggregation) often decreases their solubility and reactivity. Recently, scientists have ...

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