Abstract
A novel, versatile route to phosphorus-and carbon-substituted eta(5)-phosphacyclohexadienyl complexes was developed. Reaction of the anionic 2,4,6-triphenylphosphinine iron complex [K([18]crown-6)(thf)(2)][(CpFe)-Fe-star(PC5Ph3H2)] (1) with selected main group element electrophiles afforded the new complexes [(CpFe)-Fe-star(2-endo-H-PC5Ph3H2)] (endo-3), [(CpFe)-Fe-star(2-exo-H-PC5Ph3H2)] (exo-3), ...
Abstract
A novel, versatile route to phosphorus-and carbon-substituted eta(5)-phosphacyclohexadienyl complexes was developed. Reaction of the anionic 2,4,6-triphenylphosphinine iron complex [K([18]crown-6)(thf)(2)][(CpFe)-Fe-star(PC5Ph3H2)] (1) with selected main group element electrophiles afforded the new complexes [(CpFe)-Fe-star(2-endo-H-PC5Ph3H2)] (endo-3), [(CpFe)-Fe-star(2-exo-H-PC5Ph3H2)] (exo-3), [(CpFe)-Fe-star(1-Me-PC5Ph3H2)] (4), [(CpFe)-Fe-star(1-Me3Si-PC5Ph3H2)] (5), [(CpFe)-Fe-star(1-PPh2-PC5Ph3H2)] (6) and [(CpFe)-Fe-star(2-BCat-PC5Ph3H2)] (7, BCat = 2-benzo[d][1,3,2]dioxaborol-2-yl). Initial attack of the electrophile at phosphorus was observed, leading to a P-substitued phosphinine ligand. A subsequent rearragement occured in some cases, resulting in C-substituted phosphinine complexes endo-3, exo-3 and 7. The new complexes were characterized by H-1, P-31{H-1}, and C-13{H-1} NMR spectroscopy, UV-vis spectroscopy and elemental analysis; their molecular structures were determined by X-ray crystallography.