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Reaction of a 2,4,6-triphenylphosphinine ferrate anion with electrophiles: a new route to phosphacyclohexadienyl complexes

Hoidn, Christian M. ; Wolf, Robert


A novel, versatile route to phosphorus-and carbon-substituted eta(5)-phosphacyclohexadienyl complexes was developed. Reaction of the anionic 2,4,6-triphenylphosphinine iron complex [K([18]crown-6)(thf)(2)][(CpFe)-Fe-star(PC5Ph3H2)] (1) with selected main group element electrophiles afforded the new complexes [(CpFe)-Fe-star(2-endo-H-PC5Ph3H2)] (endo-3), [(CpFe)-Fe-star(2-exo-H-PC5Ph3H2)] (exo-3), ...


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