Go to content
UR Home

A Convenient Route to Monoalkyl-Substituted Phosphanylboranes (HRP-BH2-NMe3): Prospective Precursors to Poly[(alkylphosphino)boranes]

Stauber, Andreas ; Jurca, Titel ; Marquardt, Christian ; Fleischmann, Martin ; Seidl, Michael ; Whittell, George R. ; Manners, Ian ; Scheer, Manfred



Abstract

A simple method to access borylphosphonium iodides [RH2P-BH2 center dot NMe3]I (1a: R = Me; 1b: R = Et; 1c: R = nPr) by the addition of iodoalkanes to PH2-BH2 center dot NMe3 was developed. Complexes 1a-c were characterized by multinuclear NMR spectroscopy, and 1a and 1b additionally by single-crystal X-ray diffraction. It was possible to synthesize the Lewis-base-stabilized organosubstituted ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de

Dissertations: dissertationen@ur.de

Research data: daten@ur.de

Contact persons