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Supramolecular Synthons: Will Giant Rigid Superspheres Do?

Peresypkina, Eugenia ; Virovets, Alexander ; Scheer, Manfred


For the first time, the concept of supramolecular synthons was applied to giant rigid superspheres based on pentaphosphaferrocene [(CpFe)-Fe-R(eta(5)-P-5)] (R = Me, Et) and Cu(I) halides, which reach 2.1-3.0 nm in diameter. Two supramolecular synthons, sigma-pi and pi-pi, are discovered based on halogen center dot center dot Cp-R and Cp*center dot center dot center dot Cp* specific interactions, ...


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