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Synthesis, isolation and characterization of dinuclear oxidodiiron(III) complexes modified by monodentate pyridines

Haberberger, Michael ; Mayer, Kerstin ; Irran, Elisabeth ; Kretschmer, Robert ; Enthaler, Stephan


In the present study, iron complexes modified by differently substituted monodentate pyridine ligands containing a [Fe-O-Fe] unit have been synthesized, isolated and characterized. Noteworthy, the complexes are easily accessible by the reaction of pyridines with iron(II) chloride in the presence of molecular oxygen, which is the source for the oxido bridge as proven by labelling experiments. ...


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