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Pentaarylcyclopentadienyl Iron, Cobalt, and Nickel Halides

Chakraborty, Uttam ; Modl, Moritz ; Mühldorf, Bernd ; Bodensteiner, Michael ; Demeshko, Serhiy ; van Velzen, Niels J. C. ; Scheer, Manfred ; Harder, Sjoerd ; Wolf, Robert



Abstract

The preparation of new stable half-sandwich transition metal complexes, having a bulky cyclopentadienyl ligand C-5(C6H4-4-Et)(5) (Cp-Ar1) or C-5(C6H4-4-nBu)(5) (Cp-Ar2), is reported. The tetrahydrofuran (THF) adduct [(CpFe)-Fe-Ar1(mu-Br)(THF)](2) (1a) was synthesized by reacting K[Cp-Ar1] with [FeBr2(THF)(2)] in THF, and its molecular structure was determined by X-ray crystallography. Complex 1a ...

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