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Thorium–phosphorus triamidoamine complexes containing Th–P single- and multiple-bond interactions

Wildman, Elizabeth P. ; Balázs, Gábor ; Wooles, Ashley J. ; Scheer, Manfred ; Liddle, Stephen T.


Despite the burgeoning field of uranium-ligand multiple bonds, analogous complexes involving other actinides remain scarce. For thorium, under ambient conditions only a few multiple bonds to carbon, nitrogen, oxygen, sulfur, selenium and tellurium are reported, and no multiple bonds to phosphorus are known, reflecting a general paucity of synthetic methodologies and also problems associated with ...


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