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Pnictogen–Silicon Analogues of Benzene

Seitz, Andreas E. ; Eckhardt, Maria ; Erlebach, Andreas ; Peresypkina, Eugenia V. ; Sierka, Marek ; Scheer, Manfred


Since the discovery of the first "inorganic benzene" (borazine, B3N3H6), the synthesis of other noncarbon derivatives is an ongoing challenge in Inorganic Chemistry. Here we report on the synthesis of the first pnictogen silicon congeners of benzene, the triarsa- and the triphospha-trisilabenzene [(PhC(NtBu)(2))(3)Si3E3] (E = P (la), As (1b)) by a simple metathesis reaction. These compounds are ...


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