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Diminished electron density in the Vaska-type rhodium(I) complextrans-[Rh(NCBH3)(CO)(PPh3)2]

Galding, M. R. ; Virovets, A. V. ; Kazakov, I. V. ; Scheer, M. ; Smirnov, S. N. ; Timoshkin, A. Y.



Abstract

Vaska-type complexes, i.e. trans-[RhX(CO)(PPh3)(2)] (X is a halogen or pseudohalogen), undergo a range of reactions and exhibit considerable catalytic activity. The electron density on the Rh I atom in these complexes plays an important role in their reactivity. Many cyanotrihydridoborate (BH3CN-) complexes of Group 6-8 transition metals have been synthesized and structurally characterized, an ...

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