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Unexpected Reactivity of [(η5-1,2,4-tBu3C5H2)Ni(η3-P3)] towards Main Group Nucleophiles and by Reduction

Mädl, Eric ; Balázs, Gábor ; Peresypkina, Eugenia V. ; Scheer, Manfred


The reduction of [Cp'''Ni(eta(3)-P-3)](1; Cp''' = eta(5)-1,2,4-tBu(3)C(5)H(2)) with potassium produces the complex anion [(Cp'''Ni)(2)(mu,eta(2:2)-P-8)](2-) (2), which contains a realgar-like P-8 unit. The anionic triple-decker sandwich complex [(Cp'''Ni)(2)(mu,eta(3:3)-P-3)](-) (3) with a cyclo-P-3 middle deck is obtained when 1 is treated with NaNH2 as a nucleophile. Na[3] can subsequently be ...


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