Go to content
UR Home

Unexpected Reactivity of [(η5-1,2,4-tBu3C5H2)Ni(η3-P3)] towards Main Group Nucleophiles and by Reduction

Mädl, Eric ; Balázs, Gábor ; Peresypkina, Eugenia V. ; Scheer, Manfred



Abstract

The reduction of [Cp'''Ni(eta(3)-P-3)](1; Cp''' = eta(5)-1,2,4-tBu(3)C(5)H(2)) with potassium produces the complex anion [(Cp'''Ni)(2)(mu,eta(2:2)-P-8)](2-) (2), which contains a realgar-like P-8 unit. The anionic triple-decker sandwich complex [(Cp'''Ni)(2)(mu,eta(3:3)-P-3)](-) (3) with a cyclo-P-3 middle deck is obtained when 1 is treated with NaNH2 as a nucleophile. Na[3] can subsequently be ...

plus


Owner only: item control page
  1. Homepage UR

University Library

Publication Server

Contact:

Publishing: oa@ur.de
0941 943 -4239 or -69394

Dissertations: dissertationen@ur.de
0941 943 -3904

Research data: datahub@ur.de
0941 943 -5707

Contact persons