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CpPEt2As4-An Organic-Substituted As4Butterfly Compound

Heinl, Sebastian ; Balázs, Gábor ; Stauber, Andreas ; Scheer, Manfred


(Cp2As4)-As-PEt (Cp-PEt = C-5(4-EtC6H4)(5)) (1) is synthesized by the reaction of CpPEtC radicals with yellow arsenic (As-4). In solution an equilibrium of the starting materials and the product is found. However, 1 can be isolated and stored in the solid state without decomposition. As-4 can be easily released from 1 under thermal or photochemical conditions. From powder samples of ...


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