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Anionic Chains of Parent Pnictogenylboranes

Marquardt, Christian ; Kahoun, Tobias ; Stauber, Andreas ; Balázs, Gábor ; Bodensteiner, Michael ; Timoshkin, Alexey Y. ; Scheer, Manfred


We report on the synthesis and structural characterization of unprecedented anionic parent compounds of mixed Group 13/15 elements. The reactions of the pnictogenylboranes H2E-BH2 center dot NMe3 (1a = P, 1b = As) with phosphorus and arsenic centered nucleophiles of the type [EH2](-) (E = P, As) lead to the formation of compounds of the type [H2E-BH2-E'H-2](-) (2: E = E' = P; 3: E = E' = As; 4: E ...


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