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cyclo -P4 Building Blocks: Achieving Non-Classical Fullerene Topology and Beyond

Dielmann, Fabian ; Peresypkina, Eugenia V. ; Krämer, Barbara ; Hastreiter, Florian ; Johnson, Brian P. ; Zabel, Manfred ; Heindl, Claudia ; Scheer, Manfred



Abstract

The cyclo-P-4 complexes [(CpTa)-Ta-R(CO)(2)(eta(4)-P-4)] (Cp-R:Cp'' = 1,3-C(5)H(3)tBu(2), Cp''' = 1,2,4-C(5)H(2)tBu(3)) turned out to be predestined for the formation of hollow spherical supramolecules with non-classical fullerene-like topology. The resulting assemblies constructed with CuX (X = Cl, Br) showed a highly symmetric 32-vertex core of solely four-and six-membered rings. In some ...

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