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The Diphosphorus Complex [Cp2Mo2(CO)4(η2-P2)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers

Moussa, Mehdi Elsayed ; Attenberger, Bianca ; Fleischmann, Martin ; Schreiner, Andrea ; Scheer, Manfred


The three-component reaction of the tetrahedral diphosphorus complex [Cp2Mo2(CO)(4)(eta(2)-P-2)] (1), with Ag[BF4] (2) in the presence of 2,2'-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic ...


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