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Polymeric phosphorus chalcogenides and boracite-type inclusion compounds containing Pn4Q3 cage molecules in metal halide frameworks

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Mandal, Ria
Date of publication of this fulltext: 01 Jun 2022 06:44

Abstract (English)

This thesis introduces ternary and quaternary polymeric phosphorus chalcogenide compounds. Five such compounds,alpha-P2S6Se, beta-P2S6Se, P2S6Te, P2S6.35Se0.64, and P2S5SeTe were synthesised by using hexa-hydrated ferric chloride as mineraliser and characterised. P2S6Te is the first inorganic compound containing phosphorus and tellurium starting from elemental precursors. These phosphorus ...


Translation of the abstract (German)

Diese Arbeit stellt ternäre und quaternäre polymere Phosphorchalkogenid-Verbindungen vor. Fünf solcher Verbindungen, alpha-P2S6Se, beta-P2S6Se, P2S6Te, P2S6.35Se0.64 und P2S5SeTe wurden unter Verwendung von hexahydratisiertem Eisenchlorid als Mineralisator synthetisiert und charakterisiert. P2S6Te ist die erste anorganische Verbindung, die ausgehend von elementaren Vorläufern Phosphor und Tellur ...


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