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Dearomative Cycloadditions Utilizing an Organic Photosensitizer:
An Alternative to Iridium Catalysis

URN to cite this document:
urn:nbn:de:bvb:355-epub-433787
Rolka, Alessa B. ; König, Burkhard
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Date of publication of this fulltext: 22 Jun 2020 13:03


Abstract

A highly efficient, cheap, and organic alternative to the commonly used iridium photosensitizer (Ir[dF(CF3)ppy]2(dtbpy))PF6 ([Ir–F]) is presented for visible-light energy transfer catalysis. The organic dye 2CzPN surpasses [Ir–F] in selectivity while at the same time being easily accessible in one step. The catalyst is recyclable and, due to its uncharged nature, soluble in nonpolar solvents such ...

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