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Ab initio prediction of structuring/mesoscale inhomogeneities in surfactant-​free microemulsions and hydrogen-​bonding-​free microemulsions

Hahn, Maximilian ; Krickl, Sebastian ; Buchecker, Thomas ; Jost, Gasper ; Touraud, Didier ; Bauduin, Pierre ; Pfitzner, Arno ; Klamt, Andreas ; Kunz, Werner


In this paper, we consider the influence of H-bond donor and acceptor functionalities on the formation of mesoscale inhomogeneities in ternary systems. It was found that hydrogen-bonding re-enforces such structures, but is not necessarily a prerequisite for the occurrence of mesoscale, microemulsion-like structuring in ternary surfactant-free microemulsions (SFME) and consequently, ...


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