Synthesis of anti‐Markovnikov alcohols via epoxidation and hydrogenation of styrenes using photocatalytically generated redox equivalents

URN to cite this document:: urn:nbn:de:bvb:355-epub-438166
DOI to cite this document:: 10.5283/epub.43816

Graml, Andreas ; König, Burkhard

Preview

License: Creative Commons Attribution 4.0
PDF - Published Version
(2MB)

Date of publication of this fulltext: 25 Sep 2020 07:41

Alternative links to fulltext:DOI Publisher

This publication is part of the DEAL contract with Wiley.

Details

Preview

Indexed in

Export bibliographical data

Abstract

We report an efficient method for a formal anti-Markovnikov addition of water to styrenes through photocatalytic generation of redox equivalents, using a gold-doped titanium dioxide (Au/TiO2) semiconductor as photocatalyst. Under irradiation with UV-A light, the photocatalytic activity of Au/TiO2 generates in situ under aerobic conditions hydrogen peroxide (H2O2) and under anaerobic conditions ...