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Synthesis of anti‐Markovnikov alcohols via epoxidation and hydrogenation of styrenes using photocatalytically generated redox equivalents

URN to cite this document:
urn:nbn:de:bvb:355-epub-438166
DOI to cite this document:
10.5283/epub.43816
Graml, Andreas ; König, Burkhard
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Date of publication of this fulltext: 25 Sep 2020 07:41


Abstract

We report an efficient method for a formal anti ‐Markovnikov addition of water to styrenes through photocatalytic generation of redox equivalents, using a gold‐doped titanium dioxide (Au/TiO 2 ) semiconductor as photocatalyst. Under irradiation with UV‐A light the photocatalytic activity of Au/TiO 2 generates in situ under aerobic conditions hydrogen peroxide (H 2 O 2 ) and under anaerobic ...

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