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Synthesis of anti‐Markovnikov alcohols via epoxidation and hydrogenation of styrenes using photocatalytically generated redox equivalents

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Graml, Andreas ; König, Burkhard
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Date of publication of this fulltext: 25 Sep 2020 07:41


We report an efficient method for a formal anti ‐Markovnikov addition of water to styrenes through photocatalytic generation of redox equivalents, using a gold‐doped titanium dioxide (Au/TiO 2 ) semiconductor as photocatalyst. Under irradiation with UV‐A light the photocatalytic activity of Au/TiO 2 generates in situ under aerobic conditions hydrogen peroxide (H 2 O 2 ) and under anaerobic ...


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