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Synthesis of anti‐Markovnikov alcohols via epoxidation and hydrogenation of styrenes using photocatalytically generated redox equivalents

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Graml, Andreas ; König, Burkhard
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 25 Sep 2020 07:41

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We report an efficient method for a formal anti-Markovnikov addition of water to styrenes through photocatalytic generation of redox equivalents, using a gold-doped titanium dioxide (Au/TiO2) semiconductor as photocatalyst. Under irradiation with UV-A light, the photocatalytic activity of Au/TiO2 generates in situ under aerobic conditions hydrogen peroxide (H2O2) and under anaerobic conditions ...


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