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Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO2

Schmalzbauer, Matthias ; Svejstrup, Thomas D. ; Fricke, Florian ; Brandt, Peter ; Johansson, Magnus J. ; Bergonzini, Giulia ; König, Burkhard


Carbon dioxide (CO2) is an attractive one-carbon (C1) building block in terms of sustainability and abundance. However, its low reactivity limits applications in organic synthesis as typically high-energy reagents are required to drive transformations. Here, we present a redox-neutral C-H carboxylation of arenes and styrenes using a photocatalytic approach. Upon blue-light excitation, the ...


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