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Visible-Light-Promoted Metal-Free Synthesis of (Hetero)Aromatic Nitriles from C(sp3)−H Bonds

URN to cite this document:
urn:nbn:de:bvb:355-epub-439568
DOI to cite this document:
10.5283/epub.43956
Murugesan, Kathiravan ; Donabauer, Karsten ; König, Burkhard
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License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 22 Oct 2020 04:33


Abstract

The metal‐free activation of C(sp3)‐H bonds to value‐added products is of paramount importance in organic synthesis. Herein, we report the use of the commercially available organic dye 2,4,6‐triphenylpyrylium tetrafluoroborate (TPP) for the conversion of methylarenes to the corresponding aryl nitriles via a photocatalytic process. Applying this methodology, a variety of cyanobenzenes have been ...

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