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Visible-Light-Promoted Metal-Free Synthesis of (Hetero)Aromatic Nitriles from C(sp3)−H Bonds

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Murugesan, Kathiravan ; Donabauer, Karsten ; König, Burkhard
License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 22 Oct 2020 04:33


The metal‐free activation of C(sp3)‐H bonds to value‐added products is of paramount importance in organic synthesis. Herein, we report the use of the commercially available organic dye 2,4,6‐triphenylpyrylium tetrafluoroborate (TPP) for the conversion of methylarenes to the corresponding aryl nitriles via a photocatalytic process. Applying this methodology, a variety of cyanobenzenes have been ...


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