Visible-Light-Promoted Metal-Free Synthesis of (Hetero)Aromatic Nitriles from C(sp3)−H Bonds

URN to cite this document:: urn:nbn:de:bvb:355-epub-439568
DOI to cite this document:: 10.5283/epub.43956

Murugesan, Kathiravan ; Donabauer, Karsten ; König, Burkhard

Preview

License: Creative Commons Attribution 4.0
PDF - Published Version
(1MB)

Date of publication of this fulltext: 22 Oct 2020 04:33

Alternative links to fulltext:DOI Publisher

Details

Preview

Export bibliographical data

Abstract

The metal‐free activation of C(sp3)‐H bonds to value‐added products is of paramount importance in organic synthesis. Herein, we report the use of the commercially available organic dye 2,4,6‐triphenylpyrylium tetrafluoroborate (TPP) for the conversion of methylarenes to the corresponding aryl nitriles via a photocatalytic process. Applying this methodology, a variety of cyanobenzenes have been ...