Mixed Organometallic‐Organic Hybrid Assemblies Based on the Diarsene Complex [Cp2Mo2(CO)4(µ,ƞ2‐As2)], Ag(I) salts and N‐Donor Organic molecules

URN to cite this document:: urn:nbn:de:bvb:355-epub-443857
DOI to cite this document:: 10.5283/epub.44385

Elsayed-Mousa, Mehdi ; Shelyganov, Pavel ; Seidl, Michael ; Peresypkina, Eugenia V. ; Berg, Nele ; Gschwind, Ruth Maria

; Balazs, Gabor ; Schiller, Jana ; Scheer, Manfred

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Date of publication of this fulltext: 11 Jan 2021 06:07

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Abstract

The reaction of the organometallic diarsene complex [Cp 2 Mo 2 (CO) 4 ( h 2 ‐As 2 )] ( 1 ) (Cp = C 5 H 5 ) with Ag[Al{OC(CF 3 ) 3 } 4 ] (Ag[TEF]) yielded the Ag(I) monomer [Ag( h 2 ‐ 1 ) 3 ][TEF] ( 2 ). This compound exhibits a dynamic behaviour in solution, a feature that allows to direct a selective synthesis of unprecedented organometallic‐organic hybrid assemblies upon its reaction with ...