Mixed Organometallic‐Organic Hybrid Assemblies Based on the Diarsene Complex [Cp2Mo2(CO)4(µ,ƞ2‐As2)], Ag(I) salts and N‐Donor Organic molecules

URN to cite this document:: urn:nbn:de:bvb:355-epub-443857
DOI to cite this document:: 10.5283/epub.44385

Elsayed-Mousa, Mehdi ; Shelyganov, Pavel ; Seidl, Michael ; Peresypkina, Eugenia V. ; Berg, Nele ; Gschwind, Ruth Maria

; Balazs, Gabor ; Schiller, Jana ; Scheer, Manfred

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Date of publication of this fulltext: 11 Jan 2021 06:07

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Abstract

The reaction of the organometallic diarsene complex [Cp2Mo2(CO)(4)(eta(2)-As-2)] (1) with Ag[Al{OC(CF3)(3)}(4)] (Ag[TEF]) yielded the Ag-I monomer [Ag(eta(2)-1)(3)][TEF] (2). This compound exhibits dynamic behavior in solution, which allows directed selective synthesis of unprecedented organometallic-organic hybrid assemblies upon its reaction with N-donor organic molecules by a stepwise pathway, ...