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Coordination Behavior of a P4-Butterfly Complex towards Transition Metal Lewis Acids – Preservation versus Rearrangement

URN to cite this document:
urn:nbn:de:bvb:355-epub-444837
DOI to cite this document:
10.5283/epub.44483
Müller, Julian ; Scheer, Manfred
Date of publication of this fulltext: 20 Jan 2021 13:28

This publication is part of the DEAL contract with Wiley.


Abstract

The reactivity of the P4 butterfly complex [{Cp’’’Fe(CO)2}2(µ,η1:1‐P4)] (1, Cp’’’ = η5‐C5H2tBu3) towards divalent Co, Ni and Zn salts is investigated. The reaction with the bromide salts leads to [{Cp’’’Fe(CO)2}2(µ3,η2:1:1‐P4){MBr2}] (M = Co (2Co), Ni (2Ni), Zn (2Zn)) where the P4 butterfly scaffold is preserved. The use of the weakly ligated Co complex [Co(NCCH3)6][SbF6]2, results in the ...

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