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Cationic Functionalization by Phosphenium Ion Insertion

URN to cite this document:
urn:nbn:de:bvb:355-epub-444982
DOI to cite this document:
10.5283/epub.44498
Riesinger, Christoph ; Dütsch, Luis ; Balazs, Gabor ; Bodensteiner, Michael ; Scheer, Manfred
Date of publication of this fulltext: 21 Jan 2021 11:07

This publication is part of the DEAL contract with Wiley.


Abstract

The reaction of [Cp ''' Ni(eta(3)-P-3)] (1) with in situ generated phosphenium ions [RR ' P](+) yields the unprecedented polyphosphorus cations of the type [Cp ''' Ni(eta(3)-P4R2)][X] (R=Ph (2 a), Mes (2 b), Cy (2 c), 2,2 '-biphen (2 d), Me (2 e); [X](-)=[OTf](-), [SbF6](-), [GaCl4](-), [BArF](-), [TEF](-)) and [Cp ''' Ni(eta(3)-P4RCl)][TEF] (R=Ph (2 f), tBu (2 g)). In the reaction of 1 with ...

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