Linking of Cu(I) units by tetrahedral Mo2E2 complexes (E = P, As)

URN to cite this document:: urn:nbn:de:bvb:355-epub-445533
DOI to cite this document:: 10.5283/epub.44553

Schiller, Jana ; Schreiner, Andrea ; Seidl, Michael ; Balázs, Gábor ; Scheer, Manfred

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Date of publication of this fulltext: 22 Jan 2021 05:59

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Abstract

The reaction of [Cp2Mo2(CO)(4)(mu,eta(2:2)-E-2)] (A: E=P,B: E=As, Cp=C5H5) with the WCA-containing Cu(I)salts ([Cu(CH3CN)(4)][Al{OC(CF3)(3)}(4)] (CuTEF,C), [Cu(CH3CN)(4)][BF4] (D) and [Cu(CH3CN)(3.5)][FAl{OC6F10(C6F5)}(3)] (CuFAl,E)) affords seven unprecedented coordination compounds. Depending on the E(2)ligand complex, the counter anion of the copper salt and the stoichiometry, four dinuclear ...