The Potential of the Diarsene Complex [(C5H5)2Mo2(CO)4(µ,ƞ2-As2)] as a Connector Between Silver Ions

URN to cite this document:: urn:nbn:de:bvb:355-epub-445558
DOI to cite this document:: 10.5283/epub.44555

Elsayed-Mousa, Mehdi ; Schiller, Jana ; Peresypkina, Eugenia V. ; Seidl, Michael ; Balazs, Gabor ; Shelyganov, Pavel ; Scheer, Manfred

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Date of publication of this fulltext: 22 Jan 2021 06:14

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Abstract

The reaction of the organometallic diarsene complex [Cp2Mo2(CO)(4)(mu,eta(2)-As-2)] (B) (Cp = C5H5) with Ag[FAl{OC6F10(C6F5)}(3)] (Ag[FAl]) and Ag[Al{OC(CF3)(3)}(4)] (Ag[TEF]), respectively, yields three unprecedented supramolecular assemblies [(eta(2)-B)(4)Ag-2][FAl](2)(4), [(mu,eta(1):eta(2)-B)(3)(eta(2)-B)(2)Ag-3][TEF](3)(5) and [(mu,eta(1):eta(2)-B)(4)Ag-3][TEF](3)(6). These products are only ...