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Activation of Di‐tert‐butyldiphosphatetrahedrane: Access to (tBuCP)n (n = 2, 4) Ligand Frameworks by P‒C Bond Cleavage

URN to cite this document:
urn:nbn:de:bvb:355-epub-445744
DOI to cite this document:
10.5283/epub.44574
Hierlmeier, Gabriele ; Wolf, Robert
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Date of publication of this fulltext: 25 Jan 2021 05:43

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Abstract

The first mixed phosphatetrahedranes were reported only recently and their reactivity is virtually unexplored. Here we present a reactivity study on di‐ tert ‐butyldiphosphatetrahedrane ( 1 ), which is the dimer of tert ‐butylphosphaalkyne. The ( t BuCP) 2 tetrahedron is activated selectively by N‐heterocyclic carbene (NHC) nickel(I) and nickel(0) complexes, resulting in novel complexes featuring ...

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