| License: Creative Commons Attribution 4.0 PDF - Published Version (1MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-445755
- DOI to cite this document:
- 10.5283/epub.44575
Abstract
The reduction chemistry of the newly emerging 2‐phosphaethynolate (OCP)− is not well explored, and many unanswered questions remain about this ligand in this context. We report that reduction of [Th(TrenTIPS)(OCP)] (2, TrenTIPS=[N(CH2CH2NSiPri3)]3−), with RbC8 via [2+2+1] cycloaddition, produces an unprecedented hexathorium complex [{Th(TrenTIPS)}6(μ‐OC2P3)2(μ‐OC2P3H)2Rb4] (5) featuring four ...

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