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Stabilization of Pentaphospholes as η5 -coordinating Ligands. Stabilisierung von Pentaphospholen als η5-koordinierende Liganden

URN to cite this document:
urn:nbn:de:bvb:355-epub-445773
DOI to cite this document:
10.5283/epub.44577
Riesinger, Christoph ; Balazs, Gabor ; Bodensteiner, Michael ; Scheer, Manfred
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Date of publication of this fulltext: 25 Jan 2021 06:38

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Abstract

Electrophilic functionalisation of [Cp*Fe(eta(5)-P-5)] (1) yields the first transition-metal complexes of pentaphospholes (cyclo-P5R). Silylation of1with [(Et3Si)(2)(mu-H)][B(C6F5)(4)] leads to the ionic species [Cp*Fe(eta(5)-P5SiEt3)][B(C6F5)(4)] (2), whose subsequent reaction with H2O yields the parent compound [Cp*Fe(eta(5)-P5H)][B(C6F5)(4)] (3). The synthesis of a carbon-substituted ...

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