Metal-Deficient Supramolecule based on fivefold-symmetric Building Blocks. Ein Supermolekül mit minimaler Metallbesetzung basierend auf einem fünffach-symmetrischen Baustein

URN to cite this document:: urn:nbn:de:bvb:355-epub-445861
DOI to cite this document:: 10.5283/epub.44586

Schiller, Jana ; Peresypkina, Eugenia V.

; Virovets, Alexander V. ; Scheer, Manfred

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Date of publication of this fulltext: 25 Jan 2021 12:30

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Abstract

An unprecedented cationic supramolecule [(Cp '' Fe(eta(5)-P-5))(12){CuNCMe}(8)](8+) 2.66 nm in diameter was selectively isolated as a salt of the weakly coordinating anion [Al{OC(CF3)(3)}(4)](-) for the first time and characterized by X-ray structure analysis, PXRD, NMR spectroscopy, and mass spectrometry. Its metal-deficient core contains the lowest possible number of Cu atoms to connect 12 ...