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Element-Element Bond Formation upon Oxidation and Reduction. Element-Element-Bindungsbildung durch Oxidation und Reduktion

URN to cite this document:
urn:nbn:de:bvb:355-epub-445888
DOI to cite this document:
10.5283/epub.44588
Piesch, Martin ; Graßl, Christian ; Scheer, Manfred
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Date of publication of this fulltext: 26 Jan 2021 11:01


Abstract

The redox chemistry of [(Cp ''' Co)(2)(mu,eta(2):eta(2)-E-2)(2)] (E=P (1), As (2); Cp '''=1,2,4-tri(tert-butyl)cyclopentadienyl) was investigated. Both compounds can be oxidized and reduced twice. That way, the monocations [(Cp ''' Co)(2)(mu,eta(4):eta(4)-E-4)][X] (E=P, X=BF4 (3 a), [FAl] (3 b); E=As, X=BF4 (4 a), [FAl] (4 b)), the dications [(Cp ''' Co)(2)(mu,eta(4):eta(4)-E-4)][TEF](2) (E=P ...

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