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The Coordination Chemistry of the Phosphanylborane (C6H5)2PBH2·N(CH3)3 towards Copper(I) salts

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Elsayed-Mousa, Mehdi ; Braese, Jens ; Marquardt, Christian ; Seidl, Michael ; Scheer, Manfred
Date of publication of this fulltext: 28 Jan 2021 11:58


The reactions of the phosphinoborane Ph2PBH2 center dot NMe3 with Cu-(I) halides [CuCl, CuBr, CuI] and [Cu(CH3CN)(4)BF4], respectively, were studied. Depending on the ratio of the reactants used, the former reaction allowed for the synthesis of eight neutral coordination compounds with the general formula [CunXn(Ph2PBH2 center dot NMe3)(m)] (X = Cl, Br, I; n = 1, 2, 4, 5; m = 2, 4) (4-11). The ...


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