| License: Creative Commons Attribution 4.0 PDF - Published Version Early-view-PDF (11MB) | |
| License: Creative Commons Attribution 4.0 PDF - Published Version (11MB) |
- URN to cite this document:
- urn:nbn:de:bvb:355-epub-449076
- DOI to cite this document:
- 10.5283/epub.44907
This publication is part of the DEAL contract with Wiley.
Abstract
The one-electron oxidizing capacity of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) improves significantly by visible-light excitation. The exited-state DDQ (DDQ*) even converts benzene, fluoroarenes, heteroarenes, benzyls, and olefins into their corresponding radical cations as well as chloride and other anions into their radicals. These reactive intermediates have been utilized for the ...
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