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Excited‐state 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ*) initiated organic synthetic transformations under visible‐light irradiation

URN to cite this document:
urn:nbn:de:bvb:355-epub-449076
DOI to cite this document:
10.5283/epub.44907
Natarajan, Palani ; König, Burkhard
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Date of publication of this fulltext: 19 Feb 2021 05:50


Abstract

The one‐electron oxidizing capacity of 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone (DDQ) improves significantly by visible‐light excitation. The exited‐state DDQ (DDQ*) even converts benzene, fluoroarenes, heteroarenes, benzyls and olefins into their corresponding radical cations as well as chloride and other anions into their radicals. These reactive intermediates have been utilized for the ...

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