The Potential of Molybdenum Complexes Bearing Unsubstituted Heterodiatomic Group 15 Elements as Linkers in Supramolecular Chemistry

URN to cite this document:: urn:nbn:de:bvb:355-epub-454204
DOI to cite this document:: 10.5283/epub.45420

Elsayed Moussa, Mehdi ; Seidl, Michael ; Balázs, Gábor ; Hautmann, Matthias G.

; Scheer, Manfred

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Date of publication of this fulltext: 31 Mar 2021 16:40

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Abstract

The reactions of tetrahedral molybdenum complexes bearing unsubstituted heterodiatomic Group 15 elements, [Cp2Mo2(CO)(4)(mu,eta(2):eta(2)-PE)] (Cp=C5H5; E=As (1), Sb (2)), with Cu-I halides afforded seven unprecedented neutral supramolecular assemblies. Depending on the Mo2PE units and the Cu-I halide, the oligomers ...