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Cesium Carbonate Catalyzed Oxa‐Michael Addition of Oximes to Acrylonitrile

URN to cite this document:
urn:nbn:de:bvb:355-epub-456895
DOI to cite this document:
10.5283/epub.45689
Stahl, Jessica ; Yatham, Veera Reddy ; Crespi, Stefano ; König, Burkhard
Date of publication of this fulltext: 14 May 2021 04:17


Abstract

We report the O‐alkylation of oximes with Michael acceptors using Cs2CO3 as the catalyst. The transformation proceeds stereospecifically with retention of the oxime configuration. Irradiation with visible light in the presence of diphenyl anthracene and cerium complexes affects the E to Z configuration ratio of the oxime ether products, but a complete stereocontrol was not achieved. The ...

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