Low-Valence Anionic α-Diimine Iron Complexes: Synthesis, Characterization, and Catalytic Hydroboration Studies

URN to cite this document:: urn:nbn:de:bvb:355-epub-457109
DOI to cite this document:: 10.5283/epub.45710

Maier, Thomas M.

; Gawron, Martin ; Coburger, Peter ; Bodensteiner, Michael ; Wolf, Robert

; van Leest, Nicolaas P.

; de Bruin, Bas

; Demeshko, Serhiy ; Meyer, Franc

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Date of publication of this fulltext: 18 May 2021 07:03

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Abstract

The synthesis of rare anionic heteroleptic and homoleptic alpha-diimine iron complexes is described. Heteroleptic BIAN (bis(aryl)iminoacenaphthene) complexes 1-[K([18]c-6)-(thf)(0.5)] and 2-[K([18]c-6)(thf)(2)] were synthesized by reduction of the [(BIAN)FeBr2] precursor complex using stoichiometric amounts of potassium graphite in the presence of the corresponding olefin. The electronic ...