Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt

URN to cite this document:: urn:nbn:de:bvb:355-epub-457356
DOI to cite this document:: 10.5283/epub.45735

Ziegler, Christoph G. P.

; Maier, Thomas M.

; Pelties, Stefan ; Taube, Clemens ; Hennersdorf, Felix ; Ehlers, Andreas W. ; Weigand, Jan J. ; Wolf, Robert

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Date of publication of this fulltext: 17 May 2021 12:40

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Abstract

Rare mono- and diorganopentaphosphido cobalt complexes are accessible by P–P condensation using the unprecedented, reactive cobalt-gallium tetraphosphido complex [K(dme)2{(MesBIAN)Co(μ-η4:η2-P4)Ga(nacnac)}] (2). Compound 2 was prepared in good yield by reaction of [K(Et2O){(MesBIAN)Co(η4-1,5-cod)}] [1, BIAN = bis(mesitylimino)acenaphthene diimine, cod = 1,5-cyclooctadiene] with ...