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Synthesis of Tetrahedranes Containing the Unique Bridging Hetero‐Dipnictogen Ligand EE′ (E ≠ E′=P, As, Sb, Bi)

URN to cite this document:
urn:nbn:de:bvb:355-epub-458074
DOI to cite this document:
10.5283/epub.45807
Dütsch, Luis ; Riesinger, Christoph ; Balázs, Gábor ; Scheer, Manfred
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Date of publication of this fulltext: 19 May 2021 05:10


Abstract

New synthetic pathway towards organometallic tetrahedrane derivatives [{CpMo(CO)2}2(μ,η2:η2‐EE′)] (E≠E′=P, As, Sb, Bi) involving a hetero‐dipnictogen ligand is reported, leading to dramatic yield enhancements for already known compounds, the reduction of reaction steps and access to so far unknown AsSb, AsBi and SbBi ligand complexes, which feature unseen covalent bonds between two different ...

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