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Synthesis of Tetrahedranes Containing the Unique Bridging Hetero‐Dipnictogen Ligand EE′ (E ≠ E′=P, As, Sb, Bi)

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Dütsch, Luis ; Riesinger, Christoph ; Balázs, Gábor ; Scheer, Manfred
License: Creative Commons Attribution Non-commercial 4.0
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Date of publication of this fulltext: 19 May 2021 05:10


New synthetic pathway towards organometallic tetrahedrane derivatives [{CpMo(CO)2}2(μ,η2:η2‐EE′)] (E≠E′=P, As, Sb, Bi) involving a hetero‐dipnictogen ligand is reported, leading to dramatic yield enhancements for already known compounds, the reduction of reaction steps and access to so far unknown AsSb, AsBi and SbBi ligand complexes, which feature unseen covalent bonds between two different ...


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