Synthesis of Tetrahedranes Containing the Unique Bridging Hetero‐Dipnictogen Ligand EE′ (E ≠ E′=P, As, Sb, Bi)

URN to cite this document:: urn:nbn:de:bvb:355-epub-458074
DOI to cite this document:: 10.5283/epub.45807

Dütsch, Luis ; Riesinger, Christoph ; Balázs, Gábor ; Scheer, Manfred

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Date of publication of this fulltext: 19 May 2021 05:10

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Abstract

In order to improve and extend the rare class of tetrahedral mixed main group transition metal compounds, a new synthetic route for the complexes [{CpMo(CO)(2)}(2)(mu,eta(2):eta(2)-PE)] (E = As (1), Sb (2)) is described leading to higher yields and a decrease in reaction steps. Via this route, also the so far unknown heavier analogues containing AsSb (3a), AsBi (4) and SbBi (5) ligands, ...