Redox Chemistry of Heterobimetallic Polypnictogen Triple‐Decker Complexes – Rearrangement, Fragmentation and Transfer - University of Regensburg Publication Server

URN to cite this document:: urn:nbn:de:bvb:355-epub-458287
DOI to cite this document:: 10.5283/epub.45828

Piesch, Martin ; Reichl, Stephan ; Riesinger, Christoph ; Seidl, Michael ; Balazs, Gabor ; Scheer, Manfred

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Date of publication of this fulltext: 21 May 2021 04:56

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Abstract

The redox chemistry of the heterobimetallic triple-decker complexes [(Cp*Fe)(Cp ''' Co)(mu,eta(5):eta(4)-E-5)] (E=P (1), As (2), Cp*=1,2,3,4,5-pentamethyl-cyclopentadienyl, Cp '''=1,2,4-tri-tertbutyl-cyclopentadienyl) and [(Cp ''' Co)(Cp ''' Ni)(mu,eta(3):eta(3)-E-3)] (E=P (10), As (11)) was investigated. Compound 1 and 2 could be oxidized to the monocations 3 and 4 and further to the dications 5 ...