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Redox Chemistry of Heterobimetallic Polypnictogen Triple‐Decker Complexes – Rearrangement, Fragmentation and Transfer

URN to cite this document:
urn:nbn:de:bvb:355-epub-458287
DOI to cite this document:
10.5283/epub.45828
Piesch, Martin ; Reichl, Stephan ; Riesinger, Christoph ; Seidl, Michael ; Balazs, Gabor ; Scheer, Manfred
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Date of publication of this fulltext: 21 May 2021 04:56


Abstract

The redox chemistry of the heterobimetallic triple-decker complexes [(Cp*Fe)(Cp′′′Co)(μ,η5:η4-E5)] (E=P (1), As (2), Cp*=1,2,3,4,5-pentamethyl-cyclopentadienyl, Cp′′′=1,2,4-tri-tertbutyl-cyclopentadienyl) and [(Cp′′′Co)(Cp′′′Ni)(μ,η3:η3-E3)] (E=P (10), As (11)) was investigated. Compound 1 and 2 could be oxidized to the monocations 3 and 4 and further to the dications 5 and 6, while the initially ...

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